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Homogeneous catalytic reduction of polyoxometalate by hydrogen gas with a hydrogenase model complex

The homogeneous catalytic reduction of a polyoxometalate (POM) by hydrogen gas in aqueous media was investigated for the first time by using a [NiRu] hydrogenase model complex (I) under very mild conditions. By bubbling hydrogen gas into the buffer solution containing I and the Dawson-type POM (II(o...

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Detalles Bibliográficos
Autores principales: Minato, Takuo, Matsumoto, Takahiro, Ogo, Seiji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9065399/
https://www.ncbi.nlm.nih.gov/pubmed/35519379
http://dx.doi.org/10.1039/c9ra04396a