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Homogeneous catalytic reduction of polyoxometalate by hydrogen gas with a hydrogenase model complex
The homogeneous catalytic reduction of a polyoxometalate (POM) by hydrogen gas in aqueous media was investigated for the first time by using a [NiRu] hydrogenase model complex (I) under very mild conditions. By bubbling hydrogen gas into the buffer solution containing I and the Dawson-type POM (II(o...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9065399/ https://www.ncbi.nlm.nih.gov/pubmed/35519379 http://dx.doi.org/10.1039/c9ra04396a |