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Utilization of catecholic functionality in natural safrole and eugenol to synthesize mussel-inspired polymers

Naturally occurring safrole I upon epoxidation gave safrole oxide II, which underwent ring opening polymerization using a Lewis acid initiator/catalyst comprising of triphenylmethylphosphonium bromide/triisobutylaluminum to afford new polyether III in excellent yields. Epoxy monomer II and allyl gly...

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Detalles Bibliográficos
Autores principales: Alhaffar, Mouheddin T., Akhtar, Mohammad N., Ali, Shaikh A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066001/
https://www.ncbi.nlm.nih.gov/pubmed/35521353
http://dx.doi.org/10.1039/c9ra04719k