New molecular architectures containing low-valent cluster centres with di- and trimetalated 2-vinylpyrazine ligands: synthesis and molecular structures of Ru(5)(CO)(15)(μ(5)-C(4)H(2)N(2)CH[double bond, length as m-dash]CH)(μ-H)(2) and Ru(8)(CO)(24)(μ(7)-C(4)H(2)N(2)CH[double bond, length as m-dash]C)(μ-H)(3)

Reaction of 2-vinylpyrazine with Ru(3)(CO)(12) results in multiple C–H bond activations to afford penta- and octa-ruthenium clusters, Ru(5)(CO)(15)(μ(5)-C(4)H(2)N(2)CH[double bond, length as m-dash]CH)(μ-H)(2) (2) and Ru(8)(CO)(24)(μ(7)-C(4)H(2)N(2)CH[double bond, length as m-dash]C)(μ-H)(3) (3), in...

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Detalles Bibliográficos
Autores principales: Hossain, Md. Monir, Akter, Nahid, Ghosh, Shishir, Nesterov, Vladimir N., Richmond, Michael G., Hogarth, Graeme, Kabir, Shariff E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066017/
https://www.ncbi.nlm.nih.gov/pubmed/35515538
http://dx.doi.org/10.1039/c9ra03841h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066017/
https://www.ncbi.nlm.nih.gov/pubmed/35515538
http://dx.doi.org/10.1039/c9ra03841h

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