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Phosphonic acid mediated practical dehalogenation and benzylation with benzyl halides

For the first time, by using H(3)PO(3)/I(2) system, various benzyl chlorides, bromides and iodides were dehalogenated successfully. In the presence of H(3)PO(3), benzyl halides underwent electrophilic substitution reactions with electron-rich arenes, leading to a broad range of diarylmethanes in goo...

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Detalles Bibliográficos
Autores principales: Xiao, Jing, Ma, Yonghao, Wu, Xiaofang, Gao, Jing, Tang, Zilong, Han, Li-Biao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066657/
https://www.ncbi.nlm.nih.gov/pubmed/35519457
http://dx.doi.org/10.1039/c9ra04770k