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Computational assessments of diastereoselective [4+2] cycloaddition and 1,3-borotopic shift of a dearomatized tertiary boronic ester intermediate: reactivities explained through transition-state distortion energies
Interception of a dearomatized tertiary boronic ester, formed through a kinetically and thermodynamically favorable 1,2-metalate rearrangement/anti-S(N)2′ elimination of an activated ortho-lithiated benzyl amine, in a [4+2] cycloaddition or 1,3-borotopic shift has been investigated by density functi...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067249/ https://www.ncbi.nlm.nih.gov/pubmed/35514518 http://dx.doi.org/10.1039/c9ra03820e |