Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc)(2) followed by the formation of molecular poly-oxo cluster {U(14)} containing hemimellitate uranium(iv)

Two coordination compounds bearing tetravalent uranium were synthesized in the presence of tritopic hemimellitic acid in acetonitrile with a controlled amount of water (H(2)O/U ≈ 8) and structurally characterized. Compound 1, [U(1,2,3-Hbtc)(2)]·0.5CH(3)CN is constructed around an eight-fold coordina...

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Detalles Bibliográficos
Autores principales: Dufaye, Maxime, Martin, Nicolas P., Duval, Sylvain, Volkringer, Christophe, Ikeda-Ohno, Atsushi, Loiseau, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067251/
https://www.ncbi.nlm.nih.gov/pubmed/35514497
http://dx.doi.org/10.1039/c9ra03707a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067251/
https://www.ncbi.nlm.nih.gov/pubmed/35514497
http://dx.doi.org/10.1039/c9ra03707a

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