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Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc)(2) followed by the formation of molecular poly-oxo cluster {U(14)} containing hemimellitate uranium(iv)

Two coordination compounds bearing tetravalent uranium were synthesized in the presence of tritopic hemimellitic acid in acetonitrile with a controlled amount of water (H(2)O/U ≈ 8) and structurally characterized. Compound 1, [U(1,2,3-Hbtc)(2)]·0.5CH(3)CN is constructed around an eight-fold coordina...

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Detalles Bibliográficos
Autores principales:	Dufaye, Maxime, Martin, Nicolas P., Duval, Sylvain, Volkringer, Christophe, Ikeda-Ohno, Atsushi, Loiseau, Thierry
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067251/ https://www.ncbi.nlm.nih.gov/pubmed/35514497 http://dx.doi.org/10.1039/c9ra03707a

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