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Site-selective amination and/or nitrilation via metal-free C(sp(2))–C(sp(3)) cleavage of benzylic and allylic alcohols
Benzylic/allylic alcohols are converted via site-selective C(sp(2))–C(sp(3)) cleavage to value-added nitrogenous motifs, viz., anilines and/or nitriles as well as N-heterocycles, utilizing commercial hydroxylamine-O-sulfonic acid (HOSA) and Et(3)N in an operationally simple, one-pot process. Notably...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067586/ https://www.ncbi.nlm.nih.gov/pubmed/35655896 http://dx.doi.org/10.1039/d2sc00758d |