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Anion-coordination-driven single–double helix switching and chiroptical molecular switching based on oligoureas
Synthetic foldamers with helical conformation are widely seen, but controllable interconversion amongst different geometries (helical structure and sense) is challenging. Here, a family of oligourea (tetra-, penta-, and hexa-) ligands bearing stereocenters at both ends are designed and shown to swit...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067589/ https://www.ncbi.nlm.nih.gov/pubmed/35655878 http://dx.doi.org/10.1039/d2sc00876a |