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Nickel-catalyzed skeletal transformation of tropone derivatives via C–C bond activation: catalyst-controlled access to diverse ring systems
We report herein on nickel-catalyzed carbon–carbon bond cleavage reactions of 2,4,6-cycloheptatrien-1-one (tropone) derivatives. When a Ni/N-heterocyclic carbene catalyst is used, decarbonylation proceeds with the formation of a benzene ring, while the use of bidentate ligands in conjunction with an...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067618/ https://www.ncbi.nlm.nih.gov/pubmed/35655866 http://dx.doi.org/10.1039/d2sc01394k |