Cargando…

Rapid access to t-butylalkylated olefins enabled by Ni-catalyzed intermolecular regio- and trans-selective cross-electrophile t-butylalkylation of alkynes

Among the carbo-difunctionalization of alkynes, the stereoselective dialkylation of alkynes is the most challenging transformation due to associated competitive side reactions and thus remains underdeveloped. Herein, we report the first Ni-catalyzed regio- and trans-selective cross-dialkylation of a...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhan, Yi-Zhou, Meng, Huan, Shu, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9068203/
https://www.ncbi.nlm.nih.gov/pubmed/35655892
http://dx.doi.org/10.1039/d2sc00487a