Cargando…
Rapid access to t-butylalkylated olefins enabled by Ni-catalyzed intermolecular regio- and trans-selective cross-electrophile t-butylalkylation of alkynes
Among the carbo-difunctionalization of alkynes, the stereoselective dialkylation of alkynes is the most challenging transformation due to associated competitive side reactions and thus remains underdeveloped. Herein, we report the first Ni-catalyzed regio- and trans-selective cross-dialkylation of a...
Autores principales: | Zhan, Yi-Zhou, Meng, Huan, Shu, Wei |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9068203/ https://www.ncbi.nlm.nih.gov/pubmed/35655892 http://dx.doi.org/10.1039/d2sc00487a |
Ejemplares similares
-
Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group
por: Zhan, Yi-Zhou, et al.
Publicado: (2021) -
Regio‐ and Stereoselective Thianthrenation of Olefins To Access Versatile Alkenyl Electrophiles
por: Chen, Junting, et al.
Publicado: (2020) -
Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes
por: Zhu, Can, et al.
Publicado: (2015) -
Stereoselective Gold(I)-Catalyzed Intermolecular Hydroalkoxlation
of Alkynes
por: Veenboer, Richard M. P., et al.
Publicado: (2015) -
Highly Efficient Gold(I)-Catalyzed Regio- and Stereoselective
Hydrocarboxylation of Internal Alkynes
por: Dupuy, Stéphanie, et al.
Publicado: (2015)