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Organocatalytic stereoselective cyanosilylation of small ketones
Enzymatic stereoselectivity has typically been unrivalled by most chemical catalysts, especially in the conversion of small substrates. According to the ‘lock-and-key theory’(1,2), enzymes have confined active sites to accommodate their specific reacting substrates, a feature that is typically absen...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9068509/ https://www.ncbi.nlm.nih.gov/pubmed/35508776 http://dx.doi.org/10.1038/s41586-022-04531-5 |