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The enzyme-like catalytic hydrogen abstraction reaction mechanisms of cyclic hydrocarbons with magnesium-diluted Fe-MOF-74

Enzymatic heme and non-heme Fe(iv)–O species usually play an important role in hydrogen abstraction of biocatalytic reactions, yet duplicating the reactivity in biomimicry remains a great challenge. Based on Xiao et al.'s experimental work [Nat. Chem., 2014, 6(7), 590], we theoretically found t...

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Detalles Bibliográficos
Autores principales: Luo, Wen-zhi, Chen, Guang-hui, Xiao, Song-tao, Wang, Qiang, Huang, Ze-kun, Wang, Ling-yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9069451/
https://www.ncbi.nlm.nih.gov/pubmed/35530594
http://dx.doi.org/10.1039/c9ra04495g