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Crystal structure of μ(3)-tetra­thio­anti­monato-tris[(cyclam)zinc(II)] tetra­thio­anti­monate aceto­nitrile disolvate dihydrate showing Zn disorder over the cyclam ring planes (cyclam = 1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)

Reaction of Zn(ClO(4))(2)·6H(2)O with cyclam (cyclam = 1,4,8,11-tetra­aza­cyclo­tetra­decane, C(10)H(24)N(4)) and Na(3)SbS(4) in an aceto­nitrile/water mixture led to the formation of crystals of the title compound, [Zn(3)(SbS(4))(C(10)H(24)N(4))(3)](SbS(4))·2CH(3)CN·2H(2)O or [(Zn-cyclam)(3)(SbS(4)...

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Detalles Bibliográficos
Autores principales: Näther, Christian, Danker, Felix, Bensch, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9069514/
https://www.ncbi.nlm.nih.gov/pubmed/35547801
http://dx.doi.org/10.1107/S2056989022003759