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In Situ Studies of Arylboronic Acids/Esters and R(3)SiCF(3) Reagents: Kinetics, Speciation, and Dysfunction at the Carbanion–Ate Interface
[Image: see text] Reagent instability reduces the efficiency of chemical processes, and while much effort is devoted to reaction optimization, less attention is paid to the mechanistic causes of reagent decomposition. Indeed, the response is often to simply use an excess of the reagent. Two reaction...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9069690/ https://www.ncbi.nlm.nih.gov/pubmed/35435655 http://dx.doi.org/10.1021/acs.accounts.2c00113 |