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Novel porous organocatalysts for cycloaddition of CO(2) and epoxides

Three classes of organosilicas (DMO, OMOs and PMOs) containing immobilized multi-hydroxyl bis-(quaternary ammonium) iodide salts were prepared and tested in the cycloaddition of CO(2) and epoxides. Owing to its higher surface area, pore volume and optimum nucleophilicity of the iodide ion, OMO-2 wit...

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Detalles Bibliográficos
Autores principales: Kolle, Joel M., Sayari, Abdelhamid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9069817/
https://www.ncbi.nlm.nih.gov/pubmed/35527874
http://dx.doi.org/10.1039/c9ra05466a