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How intramolecular coordination bonding (ICB) controls the homolysis of the C–ON bond in alkoxyamines
Because the C–ON bond homolysis rate constant k(d) is an essential parameter of alkoxyamine reactivity, it is especially important to tune k(d) without a major alteration of the structure of the molecule. Recently, several approaches have become known, e.g., protonation of functional groups and form...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070044/ https://www.ncbi.nlm.nih.gov/pubmed/35530086 http://dx.doi.org/10.1039/c9ra05334d |