How intramolecular coordination bonding (ICB) controls the homolysis of the C–ON bond in alkoxyamines

Because the C–ON bond homolysis rate constant k(d) is an essential parameter of alkoxyamine reactivity, it is especially important to tune k(d) without a major alteration of the structure of the molecule. Recently, several approaches have become known, e.g., protonation of functional groups and form...

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Detalles Bibliográficos
Autores principales: Audran, Gérard, Bagryanskaya, Elena, Bagryanskaya, Irina, Edeleva, Mariya, Joly, Jean-Patrick, Marque, Sylvain R. A., Iurchenkova, Anna, Kaletina, Polina, Cherkasov, Sergey, Hai, Tung To, Tretyakov, Evgeny, Zhivetyeva, Svetlana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070044/
https://www.ncbi.nlm.nih.gov/pubmed/35530086
http://dx.doi.org/10.1039/c9ra05334d

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