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Halide exchange studies of novel Pd(ii) NNN-pincer complexes

Palladium(ii) complexes with an NNN type pincer ligand (pip(2)NNN = 2,6-bis(piperdyl-methyl)pyridine) are synthesized and characterized. Electronic and (1)H NMR spectra point to decreasing filled/filled repulsions between the dπ(Pd) orbitals and the halide lone pair orbitals along the Cl < Br <...

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Detalles Bibliográficos
Autores principales: Kuyuldar, Seher, Burda, Clemens, Connick, William B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070094/
https://www.ncbi.nlm.nih.gov/pubmed/35530079
http://dx.doi.org/10.1039/c9ra05423e