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Halide exchange studies of novel Pd(ii) NNN-pincer complexes
Palladium(ii) complexes with an NNN type pincer ligand (pip(2)NNN = 2,6-bis(piperdyl-methyl)pyridine) are synthesized and characterized. Electronic and (1)H NMR spectra point to decreasing filled/filled repulsions between the dπ(Pd) orbitals and the halide lone pair orbitals along the Cl < Br <...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070094/ https://www.ncbi.nlm.nih.gov/pubmed/35530079 http://dx.doi.org/10.1039/c9ra05423e |