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The hydrogenation of mandelonitrile over a Pd/C catalyst: towards a mechanistic understanding

A carbon supported Pd catalyst is used in the liquid phase hydrogenation of the aromatic cyanohydrin mandelonitrile (C(6)H(5)CH(OH)CH(2)CN) to afford the primary amine phenethylamine (C(6)H(5)CH(2)CH(2)NH(2)). Employing a batch reactor, the desired primary amine is produced in 87% selectivity at rea...

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Detalles Bibliográficos
Autores principales: McAllister, Mairi I., Boulho, Cédric, McMillan, Liam, Gilpin, Lauren F., Brennan, Colin, Lennon, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070305/
https://www.ncbi.nlm.nih.gov/pubmed/35531026
http://dx.doi.org/10.1039/c9ra04618f