Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes via chirality transfer from silicon to carbon

An asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes has been developed via Si-to-C chirality transfer. Mechanistic studies reveal that the silyl group migrates with retention of configuration. The stereochemical outcome of the newly formed stereogenic carbon center, which has re...

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Detalles Bibliográficos
Autores principales: Wu, Ya, Chen, Hua, Yang, Wenyu, Fan, Yu, Gao, Lu, Su, Zhishan, Hu, Changwei, Song, Zhenlei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070365/
https://www.ncbi.nlm.nih.gov/pubmed/35530994
http://dx.doi.org/10.1039/c9ra05482k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070365/
https://www.ncbi.nlm.nih.gov/pubmed/35530994
http://dx.doi.org/10.1039/c9ra05482k

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