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Ligand-free iron-catalyzed benzylic C (sp(3))–H amination of methylarenes with N-fluorobenzenesulfonimide

Direct conversion of cheap methylarenes to benzylic amines, which are essential structural units of important drugs, is of great significance. However, the known methodologies suffer from the requirement of noble metal catalysts, heavy metal residues or strong oxidants. Herein, the first biocompatib...

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Detalles Bibliográficos
Autores principales: Bao, Fengyu, Cao, Yuanbo, Liu, Wenbo, Zhu, Junhao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070760/
https://www.ncbi.nlm.nih.gov/pubmed/35530456
http://dx.doi.org/10.1039/c9ra05294a