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Metal-free oxidative cross-dehydrogenative coupling of quinones with benzylic C(sp(3))–H bonds

A metal-free cross-dehydrogenative coupling of quinones with toluene derivatives has been established. A series of quinones were subjected to reaction with toluene derivatives in the presence of di-tertbutyl peroxide (DTBP) for direct synthesis of benzylquinones. The method exhibits good functional...

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Detalles Bibliográficos
Autores principales: Dong, Yu, Yang, Jian, He, Shuai, Shi, Zhi-Chuan, Wang, Yu, Zhang, Xiao-Mei, Wang, Ji-Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9070767/
https://www.ncbi.nlm.nih.gov/pubmed/35529195
http://dx.doi.org/10.1039/c9ra05678e