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Perfluorinated phosphine and hybrid P–O ligands for Pd catalysed C–C bond forming reactions in solution and on Teflon supports

The synthesis of two types of phosphine ligands that feature perfluorinated ponytails is reported. A bidentate (RfCH(2)CH(2))(2)PCH(2)CH(2)P(CH(2)CH(2)Rf)(2) (Rf = CF(3)(CF(2))(n); n = 5, 7) and an alkoxyphosphine made by ring opening a fluorous epoxide, RfCH(2)CH(OH)CH(2)PR(2) (Rf = CF(3)(CF(2))(7)...

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Detalles Bibliográficos
Autores principales: Begum, Farzana, Ikram, Muhammad, Twamley, Brendan, Baker, Robert J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9071828/
https://www.ncbi.nlm.nih.gov/pubmed/35528399
http://dx.doi.org/10.1039/c9ra04863d