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Perfluorinated phosphine and hybrid P–O ligands for Pd catalysed C–C bond forming reactions in solution and on Teflon supports
The synthesis of two types of phosphine ligands that feature perfluorinated ponytails is reported. A bidentate (RfCH(2)CH(2))(2)PCH(2)CH(2)P(CH(2)CH(2)Rf)(2) (Rf = CF(3)(CF(2))(n); n = 5, 7) and an alkoxyphosphine made by ring opening a fluorous epoxide, RfCH(2)CH(OH)CH(2)PR(2) (Rf = CF(3)(CF(2))(7)...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9071828/ https://www.ncbi.nlm.nih.gov/pubmed/35528399 http://dx.doi.org/10.1039/c9ra04863d |