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Cap control: cyclic versus linear oligomerisation in covalent template-directed synthesis

Covalent template-directed synthesis was used to oligomerise monomer building blocks in a controlled manner to give exclusively the linear trimer. Competing reaction pathways were blocked by addition of a large excess of a monomeric capping agent. At a concentration of 1 mM, the cap selectively prev...

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Detalles Bibliográficos
Autores principales: Núñez-Villanueva, Diego, Ciaccia, Maria, Hunter, Christopher A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9071899/
https://www.ncbi.nlm.nih.gov/pubmed/35531529
http://dx.doi.org/10.1039/c9ra07233k