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Cap control: cyclic versus linear oligomerisation in covalent template-directed synthesis
Covalent template-directed synthesis was used to oligomerise monomer building blocks in a controlled manner to give exclusively the linear trimer. Competing reaction pathways were blocked by addition of a large excess of a monomeric capping agent. At a concentration of 1 mM, the cap selectively prev...
Autores principales: | Núñez-Villanueva, Diego, Ciaccia, Maria, Hunter, Christopher A. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9071899/ https://www.ncbi.nlm.nih.gov/pubmed/35531529 http://dx.doi.org/10.1039/c9ra07233k |
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