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Formation and dissociation of synthetic hetero-double-helix complex in aqueous solutions: significant effect of water content on dynamics of structural change

A 1 : 1 mixture of the ethynylhelicene pseudoenantiomers (M)-tetramer and (P)-pentamer, which possess hydrophilic terminal tri(ethyleneglycol) (TEG) groups, changes their structures in the water–THF (10 μM) solvent system between dissociated random-coils and an associated hetero-double-helix upon he...

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Detalles Bibliográficos
Autores principales: Sawato, Tsukasa, Yuzawa, Ryosuke, Kobayashi, Higashi, Saito, Nozomi, Yamaguchi, Masahiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9071914/
https://www.ncbi.nlm.nih.gov/pubmed/35528401
http://dx.doi.org/10.1039/c9ra06073a