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Synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes

This work presents a new approach to prepare mono- and disubstituted linear rigid bimetallic [2.2]paracyclophane–porphyrin conjugates via palladium-mediated Stille cross-coupling reaction. The metalated porphyrin moiety can be varied allowing convenient access to modular metal–metal fixed-distance C...

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Detalles Bibliográficos
Autores principales: Knoll, Daniel M., Wiesner, Thomas B., Marschner, Stefan M., Hassan, Zahid, Weis, Patrick, Kappes, Manfred, Nieger, Martin, Bräse, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072197/
https://www.ncbi.nlm.nih.gov/pubmed/35530211
http://dx.doi.org/10.1039/c9ra07055a