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Synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes
This work presents a new approach to prepare mono- and disubstituted linear rigid bimetallic [2.2]paracyclophane–porphyrin conjugates via palladium-mediated Stille cross-coupling reaction. The metalated porphyrin moiety can be varied allowing convenient access to modular metal–metal fixed-distance C...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072197/ https://www.ncbi.nlm.nih.gov/pubmed/35530211 http://dx.doi.org/10.1039/c9ra07055a |