Synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes

This work presents a new approach to prepare mono- and disubstituted linear rigid bimetallic [2.2]paracyclophane–porphyrin conjugates via palladium-mediated Stille cross-coupling reaction. The metalated porphyrin moiety can be varied allowing convenient access to modular metal–metal fixed-distance C...

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Autores principales: Knoll, Daniel M., Wiesner, Thomas B., Marschner, Stefan M., Hassan, Zahid, Weis, Patrick, Kappes, Manfred, Nieger, Martin, Bräse, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072197/
https://www.ncbi.nlm.nih.gov/pubmed/35530211
http://dx.doi.org/10.1039/c9ra07055a
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author Knoll, Daniel M.
Wiesner, Thomas B.
Marschner, Stefan M.
Hassan, Zahid
Weis, Patrick
Kappes, Manfred
Nieger, Martin
Bräse, Stefan
author_facet Knoll, Daniel M.
Wiesner, Thomas B.
Marschner, Stefan M.
Hassan, Zahid
Weis, Patrick
Kappes, Manfred
Nieger, Martin
Bräse, Stefan
author_sort Knoll, Daniel M.
collection PubMed
description This work presents a new approach to prepare mono- and disubstituted linear rigid bimetallic [2.2]paracyclophane–porphyrin conjugates via palladium-mediated Stille cross-coupling reaction. The metalated porphyrin moiety can be varied allowing convenient access to modular metal–metal fixed-distance Cu/Zn complexes.
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spelling pubmed-90721972022-05-06 Synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes Knoll, Daniel M. Wiesner, Thomas B. Marschner, Stefan M. Hassan, Zahid Weis, Patrick Kappes, Manfred Nieger, Martin Bräse, Stefan RSC Adv Chemistry This work presents a new approach to prepare mono- and disubstituted linear rigid bimetallic [2.2]paracyclophane–porphyrin conjugates via palladium-mediated Stille cross-coupling reaction. The metalated porphyrin moiety can be varied allowing convenient access to modular metal–metal fixed-distance Cu/Zn complexes. The Royal Society of Chemistry 2019-09-26 /pmc/articles/PMC9072197/ /pubmed/35530211 http://dx.doi.org/10.1039/c9ra07055a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Knoll, Daniel M.
Wiesner, Thomas B.
Marschner, Stefan M.
Hassan, Zahid
Weis, Patrick
Kappes, Manfred
Nieger, Martin
Bräse, Stefan
Synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes
title Synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes
title_full Synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes
title_fullStr Synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes
title_full_unstemmed Synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes
title_short Synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes
title_sort synthesis and characterization of rigid [2.2]paracyclophane–porphyrin conjugates as scaffolds for fixed-distance bimetallic complexes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072197/
https://www.ncbi.nlm.nih.gov/pubmed/35530211
http://dx.doi.org/10.1039/c9ra07055a
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