Iron-catalysed allylation–hydrogenation sequences as masked alkyl–alkyl cross-couplings

An iron-catalysed allylation of organomagnesium reagents (alkyl, aryl) with simple allyl acetates proceeds under mild conditions (Fe(OAc)(2) or Fe(acac)(2), Et(2)O, r.t.) to furnish various alkene and styrene derivatives. Mechanistic studies indicate the operation of a homotopic catalyst. The sequen...

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Detalles Bibliográficos
Autores principales: Bernauer, Josef, Wu, Guojiao, Jacobi von Wangelin, Axel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072617/
https://www.ncbi.nlm.nih.gov/pubmed/35527959
http://dx.doi.org/10.1039/c9ra07604b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072617/
https://www.ncbi.nlm.nih.gov/pubmed/35527959
http://dx.doi.org/10.1039/c9ra07604b

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