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High-yielding Pd(2)(dba)(3)·C(6)H(6)-based four-fold Sonogashira coupling with selenophene-conjugated magnesium tetraethynylporphyrin for organic solar cells

A catalytic system using Pd(2)(dba)(3)·(C(6)H(6))/PPh(3)/CuI for Sonogashira coupling was demonstrated to synthesize a selenophene-conjugated magnesium tetraethynylporphyrin Mg-TEP-(Se-DPP)(4) (2a). The catalytic system enabled four-fold cross-coupling of the four terminal alkynes of magnesium tetra...

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Detalles Bibliográficos
Autores principales: Wang, Huan, Nakagawa, Takafumi, Zhang, Meng-Meng, Ogumi, Keisuke, Yang, Shangfeng, Matsuo, Yutaka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9073152/
https://www.ncbi.nlm.nih.gov/pubmed/35529715
http://dx.doi.org/10.1039/c9ra07393k