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Stabilization of two conformers via intra- or inter-molecular hydrogen bonds in a dinuclear vanadium(v) complex with a pendant Schiff base: theoretical insight

A dinuclear vanadium(v) complex, (μ-O)(2)[V(O)(L)](2), [where HL = 2-methoxy-6-((2-(2-hydroxyethylamino)ethylimino)methyl)phenol] has been synthesized and characterized by spectral and elemental analysis. A single crystal X-ray diffraction study confirms it structure. Two different conformations, st...

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Detalles Bibliográficos
Autores principales: Thakur, Snehasish, Drew, Michael G. B., Franconetti, Antonio, Frontera, Antonio, Chattopadhyay, Shouvik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9074122/
https://www.ncbi.nlm.nih.gov/pubmed/35530693
http://dx.doi.org/10.1039/c9ra07006k