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Unusual adsorption behaviours and responsive structural dynamics via selective gate effects of an hourglass porous metal–organic framework
An hourglass porous metal–organic framework, LIFM-12, constructed on a T-shaped flexible ligand with Cu(2+) paddle-wheel clusters, shows temperature and gas adsorption responsive structural dynamics upon reversible molecular guest binding. Temperature-dependent single crystal and powder X-ray diffra...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9075530/ https://www.ncbi.nlm.nih.gov/pubmed/35542309 http://dx.doi.org/10.1039/c9ra07301a |