Unusual adsorption behaviours and responsive structural dynamics via selective gate effects of an hourglass porous metal–organic framework

An hourglass porous metal–organic framework, LIFM-12, constructed on a T-shaped flexible ligand with Cu(2+) paddle-wheel clusters, shows temperature and gas adsorption responsive structural dynamics upon reversible molecular guest binding. Temperature-dependent single crystal and powder X-ray diffra...

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Detalles Bibliográficos
Autores principales: Xiong, Ying, Fan, Yan-Zhong, Wei, Zhang-Wen, Chen, Cheng-Xia, Chen, Sha, Wang, Dawei, Barboiu, Mihail, Jiang, Ji-Jun, Su, Cheng-Yong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9075530/
https://www.ncbi.nlm.nih.gov/pubmed/35542309
http://dx.doi.org/10.1039/c9ra07301a

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