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Rotational dynamics of the organic bridging linkers in metal–organic frameworks and their substituent effects on the rotational energy barrier
Organic bridging linkers or ligands play an important role in gas and fuel storage, CO(2) capture, and controlling the radical polymerization reactions in metal–organic frameworks (MOFs) nanochannels. The rotation of the linkers causes the expansion of the pore size and pore volume in MOFs. To under...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9075868/ https://www.ncbi.nlm.nih.gov/pubmed/35541820 http://dx.doi.org/10.1039/c9ra01288e |