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A novel synthetic strategy for hydroxyl-terminated polybutadiene containing high cis-1,4 contents based on a Ni(ii)-coordinated anionic initiating system

In this study, novel hydroxyl-terminated polybutadiene (HTPB) with a high cis-1,4 content was developed using a tert-butyl dimethyl siloxy dimethyl propyl lithium (Li)–naphthenate nickel (Ni)–boron trifluoride (B) initiating system (Li–Ni–B). The effects of the material ratio and the addition sequen...

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Detalles Bibliográficos
Autor principal: Min, Xin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9075970/
https://www.ncbi.nlm.nih.gov/pubmed/35540646
http://dx.doi.org/10.1039/c9ra04531g