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Isolation and enantiostability of the B-chiral bis(salicylato)borate anions [B(R)(Sal)(2)] and [B(S)(Sal)(2)]

The chiral spiroborate anions [B(S)(Sal)(2)] and [B(R)(Sal)(2)], (R and S subscripts indicate boron stereochemistry) have been isolated as 1 : 1 quininium and 1 : 2 sparteinium salts, [HQuin][B(S)(Sal)(2)] and [H(2)Spa][B(R)(Sal)(2)](2) respectively, by either cation metathesis or a simple one-pot s...

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Detalles Bibliográficos
Autores principales: Wong, Lawrence W.-Y., Au Yeung, Alex S.-F., Tam, Gemma S.-S., Kan, Jack W.-H., Sung, Herman H.-Y., Sheong, Fu Kit, Lin, Zhenyang, Williams, Ian D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077088/
https://www.ncbi.nlm.nih.gov/pubmed/35540877
http://dx.doi.org/10.1039/c7ra11997f