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Isolation and enantiostability of the B-chiral bis(salicylato)borate anions [B(R)(Sal)(2)] and [B(S)(Sal)(2)]
The chiral spiroborate anions [B(S)(Sal)(2)] and [B(R)(Sal)(2)], (R and S subscripts indicate boron stereochemistry) have been isolated as 1 : 1 quininium and 1 : 2 sparteinium salts, [HQuin][B(S)(Sal)(2)] and [H(2)Spa][B(R)(Sal)(2)](2) respectively, by either cation metathesis or a simple one-pot s...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077088/ https://www.ncbi.nlm.nih.gov/pubmed/35540877 http://dx.doi.org/10.1039/c7ra11997f |