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A pillared-layered copper(i) halide-based metal–organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift

We report a new copper halide-based compound [Cu(6)I(6)Br(2)C(16)H(32)N(4)] (1) with a 3D 2-fold interpenetrated framework structure. Upon excitation at 290 nm and 350 nm, compound 1 shows dual emission at ca. 500 nm and ca. 530 nm. As the temperature decreased from 300 K down to 6 K, the luminescen...

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Detalles Bibliográficos
Autores principales: Xin, Bingjing, Sang, Jianwei, Gao, Yi, Li, Guanghua, Shi, Zhan, Feng, Shouhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077280/
https://www.ncbi.nlm.nih.gov/pubmed/35542574
http://dx.doi.org/10.1039/c7ra11950j