A pillared-layered copper(i) halide-based metal–organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift

We report a new copper halide-based compound [Cu(6)I(6)Br(2)C(16)H(32)N(4)] (1) with a 3D 2-fold interpenetrated framework structure. Upon excitation at 290 nm and 350 nm, compound 1 shows dual emission at ca. 500 nm and ca. 530 nm. As the temperature decreased from 300 K down to 6 K, the luminescen...

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Detalles Bibliográficos
Autores principales: Xin, Bingjing, Sang, Jianwei, Gao, Yi, Li, Guanghua, Shi, Zhan, Feng, Shouhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077280/
https://www.ncbi.nlm.nih.gov/pubmed/35542574
http://dx.doi.org/10.1039/c7ra11950j
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author Xin, Bingjing
Sang, Jianwei
Gao, Yi
Li, Guanghua
Shi, Zhan
Feng, Shouhua
author_facet Xin, Bingjing
Sang, Jianwei
Gao, Yi
Li, Guanghua
Shi, Zhan
Feng, Shouhua
author_sort Xin, Bingjing
collection PubMed
description We report a new copper halide-based compound [Cu(6)I(6)Br(2)C(16)H(32)N(4)] (1) with a 3D 2-fold interpenetrated framework structure. Upon excitation at 290 nm and 350 nm, compound 1 shows dual emission at ca. 500 nm and ca. 530 nm. As the temperature decreased from 300 K down to 6 K, the luminescent properties of compound 1 show large red shifts of 120 nm and 72 nm, respectively.
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spelling pubmed-90772802022-05-09 A pillared-layered copper(i) halide-based metal–organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift Xin, Bingjing Sang, Jianwei Gao, Yi Li, Guanghua Shi, Zhan Feng, Shouhua RSC Adv Chemistry We report a new copper halide-based compound [Cu(6)I(6)Br(2)C(16)H(32)N(4)] (1) with a 3D 2-fold interpenetrated framework structure. Upon excitation at 290 nm and 350 nm, compound 1 shows dual emission at ca. 500 nm and ca. 530 nm. As the temperature decreased from 300 K down to 6 K, the luminescent properties of compound 1 show large red shifts of 120 nm and 72 nm, respectively. The Royal Society of Chemistry 2018-01-08 /pmc/articles/PMC9077280/ /pubmed/35542574 http://dx.doi.org/10.1039/c7ra11950j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Xin, Bingjing
Sang, Jianwei
Gao, Yi
Li, Guanghua
Shi, Zhan
Feng, Shouhua
A pillared-layered copper(i) halide-based metal–organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift
title A pillared-layered copper(i) halide-based metal–organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift
title_full A pillared-layered copper(i) halide-based metal–organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift
title_fullStr A pillared-layered copper(i) halide-based metal–organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift
title_full_unstemmed A pillared-layered copper(i) halide-based metal–organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift
title_short A pillared-layered copper(i) halide-based metal–organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift
title_sort pillared-layered copper(i) halide-based metal–organic framework exhibiting dual emission, and piezochromic and thermochromic properties with a large temperature-dependent emission red-shift
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077280/
https://www.ncbi.nlm.nih.gov/pubmed/35542574
http://dx.doi.org/10.1039/c7ra11950j
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