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Radical-initiated alkene hydroauration as a route to gold(iii) alkyls: an experimental and computational study
The hydroauration of functionalised 1-alkenes by the gold(iii) hydride (C^N(OMe)^C)AuH is initiated by organic radicals and proceeds via (C^N^C)Au(ii) radical intermediates following a bimolecular outer-sphere mechanism. The outcome of these reactions is determined by the stability of the gold-subst...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077454/ https://www.ncbi.nlm.nih.gov/pubmed/35541449 http://dx.doi.org/10.1039/c7ra13481a |