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Desymmetrisation of meso-diones promoted by a highly recyclable polymer-supported chiral phosphoric acid catalyst

A polystyrene-supported BINOL-derived chiral phosphoric acid has been applied to the desymmetrisation of meso-diones to produce enantioenriched cyclohexenones. The catalytic resin has proven highly active and robust, giving rise to Hajos–Parrish or Wieland–Miescher type products in good yields and e...

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Detalles Bibliográficos
Autores principales: Clot-Almenara, Lidia, Rodríguez-Escrich, Carles, Pericàs, Miquel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078317/
https://www.ncbi.nlm.nih.gov/pubmed/35540356
http://dx.doi.org/10.1039/c7ra13471a