Cargando…
Desymmetrisation of meso-diones promoted by a highly recyclable polymer-supported chiral phosphoric acid catalyst
A polystyrene-supported BINOL-derived chiral phosphoric acid has been applied to the desymmetrisation of meso-diones to produce enantioenriched cyclohexenones. The catalytic resin has proven highly active and robust, giving rise to Hajos–Parrish or Wieland–Miescher type products in good yields and e...
Autores principales: | Clot-Almenara, Lidia, Rodríguez-Escrich, Carles, Pericàs, Miquel A. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2018
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078317/ https://www.ncbi.nlm.nih.gov/pubmed/35540356 http://dx.doi.org/10.1039/c7ra13471a |
Ejemplares similares
-
The use of chiral lithium amides in the desymmetrisation of N-trialkylsilyl dimethyl sulfoximines
por: McGrath, Matthew J, et al.
Publicado: (2007) -
Desymmetrised pentaporphyrinic gears mounted on metallo-organic anchors
por: Abid, Seifallah, et al.
Publicado: (2021) -
Enzymatic Desymmetrising Redox Reactions for the Asymmetric Synthesis of Biaryl Atropisomers
por: Staniland, Samantha, et al.
Publicado: (2014) -
A fully recyclable heterogenized Cu catalyst for the general carbene transfer reaction in batch and flow
por: Maestre, Lourdes, et al.
Publicado: (2015) -
Continuous flow enantioselective arylation of aldehydes with ArZnEt using triarylboroxins as the ultimate source of aryl groups
por: Rolland, Julien, et al.
Publicado: (2009)