High-resolution X-ray diffraction determination of the electron density of 1-(8-PhSC(10)H(6))SS(C(10)H(6)SPh-8′)-1′ with the QTAIM approach: evidence for S(4) σ(4c–6e) at the naphthalene peri-positions

An extended hypervalent S(4) σ(4c–6e) system was confirmed for the linear (B)S-∗-(A)S-∗-(A)S-∗-(B)S interaction in 1-(8-Ph(B)SC(10)H(6))(A)S–(A)S(C(10)H(6)(B)SPh-8′)-1′ (1) via high-resolution X-ray diffraction determination of electron densities. The presence of bond critical points (BCPs; ∗) on th...

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Detalles Bibliográficos
Autores principales: Tsubomoto, Yutaka, Hayashi, Satoko, Nakanishi, Waro, Mapp, Lucy K., Coles, Simon J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078645/
https://www.ncbi.nlm.nih.gov/pubmed/35540809
http://dx.doi.org/10.1039/c7ra13636f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078645/
https://www.ncbi.nlm.nih.gov/pubmed/35540809
http://dx.doi.org/10.1039/c7ra13636f

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