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High-resolution X-ray diffraction determination of the electron density of 1-(8-PhSC(10)H(6))SS(C(10)H(6)SPh-8′)-1′ with the QTAIM approach: evidence for S(4) σ(4c–6e) at the naphthalene peri-positions
An extended hypervalent S(4) σ(4c–6e) system was confirmed for the linear (B)S-∗-(A)S-∗-(A)S-∗-(B)S interaction in 1-(8-Ph(B)SC(10)H(6))(A)S–(A)S(C(10)H(6)(B)SPh-8′)-1′ (1) via high-resolution X-ray diffraction determination of electron densities. The presence of bond critical points (BCPs; ∗) on th...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078645/ https://www.ncbi.nlm.nih.gov/pubmed/35540809 http://dx.doi.org/10.1039/c7ra13636f |