Catalytic enantioselective Henry reaction of α-keto esters, 2-acylpyridines and 2-acylpyridine N-oxides

A pre-prepared Ni–PyBisulidine complex has been developed for the catalytic asymmetric Henry reaction of α-keto esters, 2-acylpyridines and 2-acylpyridine N-oxides. The corresponding β-nitro-α-hydroxy esters were obtained in good to excellent yields (up to 99%) with a high enantiomeric excess (ee) (...

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Detalles Bibliográficos
Autores principales: He, Feilong, Chen, Guanghui, Yang, Junxia, Liang, Guojuan, Deng, Ping, Xiong, Yan, Zhou, Hui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078658/
https://www.ncbi.nlm.nih.gov/pubmed/35541881
http://dx.doi.org/10.1039/c8ra00552d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078658/
https://www.ncbi.nlm.nih.gov/pubmed/35541881
http://dx.doi.org/10.1039/c8ra00552d

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