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Insight into catalytic reduction of CO(2) to methane with silanes using Brookhart's cationic Ir(iii) pincer complex
Using density functional theory computations, we investigated in detail the underlying reaction mechanism and crucial intermediates present during the reduction of carbon dioxide to methane with silanes, catalyzed by the cationic Ir-pincer complex ((POCOP)Ir(H)(acetone)(+), POCOP = 2,6-bis(dibutylph...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9078678/ https://www.ncbi.nlm.nih.gov/pubmed/35541860 http://dx.doi.org/10.1039/c7ra13486j |